Showing posts with label TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM. Show all posts
Showing posts with label TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM. Show all posts

Monday, March 5, 2012

Where to buy TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM?

TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM is the chemical compound with the formula Pt(P(C6H5)3)4, often abbreviated Pt(PPh3)4. The bright yellow compound is widely used as a precursor to other platinum complexes.
The molecule is tetrahedral, with point group symmetry of Td, as expected for a four-coordinate metal complex of a metal with the d10 configuration. Even though this complex follows the 18 electron rule, it dissociates triphenylphosphine in solution to give the 16e− derivative containing only three PPh3 ligands: Pt(PPh3)4 → Pt(PPh3)3 + PPh3
The complex is typically prepared in one-pot reaction from potassium tetrachloroplatinate(II). Reduction of TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM with alkaline ethanol in the presence of excess triphenylphosphine affords the product as a precipitate. The reaction occurs in two distinct steps. In the first step, PtCl2(PPh3)2 is generated. In the second step, this platinum(II) complex is reduced. The overall synthesis can be summarized as:
K2[PtCl4] + 2KOH + 4PPh3 + C2H5OH → Pt(PPh3)4 + 4KCl + CH3CHO + 2H2O
More about: TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM sale
Read more: Best Chemicals